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1

Palladium-catalyzed intramolecular cyanosilylation of alkynes leading to stereoselective synthesis of α,β-unsaturated nitriles

Michinori Suginome, Hiroshi Kinugasa, Yoshihiko Ito

Journal:

Tetrahedron Letters

Year:

1994

Language:

english

File:

PDF, 232 KB

english, 1994

2

Photoinduced molecular transformations. Part 107. A versatile substitution of a carbonyl group of steroidal ketones by a heteroatom. The synthesis of aza-, oxa-, thia-, selena-, and tellurasteroids

Suginome, Hiroshi, Yamada, Shinji, Wang, Jian Bo

Journal:

Journal of Organic Chemistry

Year:

1990

Language:

english

File:

PDF, 1013 KB

english, 1990

3

Encyclopedia of Reagents for Organic Synthesis || Mercury(II) Oxide-Bromine

Suginome, Hiroshi

Year:

2001

Language:

english

File:

PDF, 51 KB

english, 2001

4

A new photoinduced rearrangement of steroidal ?,?-unsaturated cyclic ketone oximes into the ?,?-unsaturated isomer involving an intramolecular stereospecific hydrogen transfer

Suginome, Hiroshi, Ohki, Takashi

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1988

Language:

english

File:

PDF, 257 KB

english, 1988

5

Photoinduced transformations. Part 41. Photo-Beckmann rearrangement of some cholestan-3-one oximes with methyl groups attached to the ?-carbon

Suginome, Hiroshi, Takahashi, Yukoh

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1979

Language:

english

File:

PDF, 764 KB

english, 1979

6

Photolysis of Nitrite Esters bearing Nitrogen on the β-Carbon

Suginome, Hiroshi, Murakami, Masakazu, Masamune, Tadashi

Journal:

Bulletin of the Chemical Society of Japan

Year:

1968

Language:

english

File:

PDF, 16.42 MB

english, 1968

7

Platinkatalysierte regioselektive Silaborierung von Alkenen

Dr. Michinori Suginome, Hiroshi Nakamura, Prof. Dr. Yoshihiko Ito

Journal:

Angewandte Chemie

Year:

1997

File:

PDF, 354 KB

1997

8

Platinum-Catalyzed Regioselective Silaboration of Alkenes

Dr. Michinori Suginome, Hiroshi Nakamura, Prof. Dr. Yoshihiko Ito

Journal:

Angewandte Chemie International Edition

Year:

1997

Language:

english

File:

PDF, 377 KB

english, 1997

9

ChemInform Abstract: Tandem Cyclization of N-Allylaminyl Radicals: Stereoselective Synthesis of 1,2,5-Trisubstituted Pyrrolizidines.

Hisanori Senboku, Yoshinori Kajizuka, Hikaru Hasegawa, Hirotake Fujita, Hiroshi Suginome, Kazuhiko Orito, Masao Tokuda

Journal:

Year:

1999

File:

PDF, 32 KB

1999

10

ChemInform Abstract: Regio- and Stereoselective Synthesis of (Z)-β-Silylalkenylboranes by Silaboration of Alkynes Catalyzed by Palladium and Platinum Complexes.

Michinori Suginome, Takanori Matsuda, Hiroshi Nakamura, Yoshihiko Ito

Journal:

Year:

1999

Language:

english

File:

PDF, 40 KB

english, 1999

11

ChemInform Abstract: Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon—Boron Bonds.

Michinori Suginome, Takeshi Fukuda, Hiroshi Nakamura, Yoshihiko Ito

Journal:

Year:

2000

File:

PDF, 34 KB

2000

12

ChemInform Abstract: Benzolactams. Part 4. Reaction of 3′,4′- or 4′,5′-Dialkoxy-Substituted 1-(2′-Bromobenzyl)-2-ethoxycarbonyl-1,2,3,4-tetrahydroisoquinolines with Alkyllithium. 1,2 and 1,4 Additions of Alkyllithium to Benzolactams.

Kazuhiko Orito, Mamoru Miyazawa, Ryo Kanbayashi, Takashi Tatsuzawa, Masao Tokuda, Hiroshi Suginome

Journal:

Year:

2001

File:

PDF, 37 KB

2001

13

Remote Functionalization by Alkoxyl Radicals Generated by the Photolysis of Nitrite Esters: The Barton Reaction and Related Reactions of Nitrite Esters

Hiroshi Suginome

Journal:

Year:

2004

File:

PDF, 52 KB

2004

14

E/Z-Isomerization and Accompanying Photoreactions of Oximes, Oxime Ethers, Nitrones, Hydrazones, Imines, Azo- and Azoxy Compounds, and Various Applications

Hiroshi Suginome

Journal:

Year:

2004

File:

PDF, 51 KB

2004

15

Photo-induced molecular transformations. Part 123. One-step synthesis of 1H-benz[f]indole-4,9-diones by a new regioselective photoaddition of 2-amino-1,4-naphthoquinone with various alkenes and its application to one-step synthesis of kinamycin skeleton

Kazuhiro Kobayashi, Hiroyasu Takeuchi, Shinzo Seko, Hiroshi Suginome

Journal:

Helvetica Chimica Acta

Year:

1991

Language:

english

File:

PDF, 193 KB

english, 1991

16

Photoinduced Molecular Transformations. Part 142. One-step syntheses of 1H-benz[f]indole-4,9-diones and 1H-indole-4,7-diones by a new regioselective photoaddition of 2-amino-1,4-naphthoquinones and 2-amino-1,4-benzoquinones with alkenes

Kazuhiro Kobayashi, Hiroyasu Takeuchi, Shinzo Seko, Yoshikazu Kanno, Sachiko Kujime, Hiroshi Suginome

Journal:

Helvetica Chimica Acta

Year:

1993

Language:

english

File:

PDF, 533 KB

english, 1993

17

Photoinduced molecular transformations. Part 156. New photoadditions of 2-hydroxy-1,4-naphthoquinones with naphthols and their derivatiyes

Hiroshi Suginome, Atsushi Konishi, Hideo Sakurai, Hiroki Minakawa, Toshihiro Takeda, Hisanori Senboku, Masao Tokuda, Kazuhiro Kobayashi

Journal:

Year:

1995

Language:

english

File:

PDF, 442 KB

english, 1995

18

Studies on carboxylation of alkoxy-substituted benzyl alcohols via direct lithiation and bromine-lithium exchange: Synthesis of phthalides and phthalideisoquinoline alkaloids

Kazuhiko Orito, Mamoru Miyazawa, Hiroshi Suginome

Journal:

Year:

1995

Language:

english

File:

PDF, 410 KB

english, 1995

19

A stereospecific synthesis of conjugated (E, Z)- and (Z, Z)-alikadienes by a palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with 1-alkenyl bromides

Norio Miyaura, Hiroshi Suginome, Akira Suzuki

Journal:

Tetrahedron Letters

Year:

1981

Language:

english

File:

PDF, 234 KB

english, 1981

20

Replacement of a carbonyl group of cyclic ketones by an oxygen atom: A four-step transformation of cyclic ketones into cyclic ethers

Hiroshi Suginome, Shinji Yamada

Journal:

Tetrahedron Letters

Year:

1984

Language:

english

File:

PDF, 212 KB

english, 1984

21

A new aromatization of ring-A of steroids. Synthesis of estrone

Hiroshi Suginome, Hisanori Senboku, Shinji Yamada

Journal:

Tetrahedron Letters

Year:

1988

Language:

english

File:

PDF, 145 KB

english, 1988

22

Regioselective synthesis of β,γ-unsaturated acids by the electrochemical carboxylation of allylic bromides using a reactive-metal anode

Masao Tokuda, Takashi Kabuki, Yoshitaka Katoh, Hiroshi Suginome

Journal:

Tetrahedron Letters

Year:

1995

Language:

english

File:

PDF, 187 KB

english, 1995

23

Cross-coupling reactions of 1-alkenylboranes with 3,4-epoxy-1-butene catalyzed by palladium or nickel complexes

Norio Miyaura, Yutaka Tanabe, Hiroshi Suginome, Akira Suzuki

Journal:

Journal of Organometallic Chemistry

Year:

1982

Language:

english

File:

PDF, 284 KB

english, 1982

24

New short step general synthesis of isobenzofuran-1(3H)-ones (phthalides) based on a single or double β-scission of alkoxyl radicals generated from 1-ethyl-benzocyclobuten-1-ols and from 1,3-dihydroisobenzofuran-1-ols; synthesis of some natural phthalides

Kazuhiro Kobayashi, Masahito Itoh, Akiyoshi Sasaki, Hiroshi Suginome

Journal:

Year:

1991

Language:

english

File:

PDF, 1.03 MB

english, 1991

25

New general synthesis of medium ring-lactones via a regioselective β-scission of alkoxyl radicals generated from catacondensed lactols

Hiroshi Suginome, Shinji Yamada

Journal:

Year:

1987

Language:

english

File:

PDF, 1.17 MB

english, 1987

26

Photoinduced molecular transformations. Part 150. A new total synthesis of (±)-α-Himachalene based on a Sequence involving [2+2] photoaddition and regioselective β-scission of alkoxyl radicals generated from the resulting cyclobutanols

Hiroshi Suginome, Yutaka Nakayama

Journal:

Year:

1994

Language:

english

File:

PDF, 800 KB

english, 1994

27

Photoinduced molecular transformations. Part 151. One-pot synthesis of 1H-benz[g]indole-4,5-diones by a regioselective (3+2) photoaddition of 4

Hiroshi Suginome, Hideo Sakurai, Akiyoshi Sasaki, Hiroyasu Takeuchi, Kazuhiro Kobayashi

Journal:

Year:

1994

Language:

english

File:

PDF, 578 KB

english, 1994

28

New total synthesis of (+)-N-methylanisomycin by anodic cyclization of δ-alkenylamine

Masao Tokuda, Hirotake Fujita, Tohru Miyamoto, Hiroshi Suginome

Journal:

Year:

1993

Language:

english

File:

PDF, 1.08 MB

english, 1993

29

Stereoselective synthesis of 4- or 5-substituted 2-benzyl- and 2-benzoylpyrrolidines by means of anodic oxidation of δ-alkenylamines

Masao Tokuda, Tohru Miyamoto, Hirotake Fujita, Hiroshi Suginome

Journal:

Year:

1991

Language:

english

File:

PDF, 701 KB

english, 1991

30

Photoinduced molecular transformations. Part 154. On the mechanism of the formation of the 5-iodopentyl formate in the photolysis of cyclopentanol hypoiodite in solution in the presence of mercury(II) oxide-iodine.

Hiroshi Suginome, Hisanori Senboku

Journal:

Year:

1994

Language:

english

File:

PDF, 869 KB

english, 1994

31

A new route to γ-substituted γ-lactones and δ-substituted δ-lactones based on the regioselective β-scission of alkoxyl radicals generated from transannular hemiacetals

Kazuhiro Kobayashi, Akiyoshi Sasaki, Yoshikazu Kanno, Hiroshi Suginome

Journal:

Year:

1991

Language:

english

File:

PDF, 695 KB

english, 1991

32

Cyclization of aminyl radicals generated by anodic oxidation of lithium alkenylamides. Stereo- and regioselective synthesis of cis-l-alkyl-2, 5-disubstituted pyrrolidines

Masao Tokuda, Yasufumi Yamada, Toshiya Takagi, Hiroshi Suginome, Akio Furusaki

Journal:

Year:

1987

Language:

english

File:

PDF, 1.23 MB

english, 1987

33

New stereospecific syntheses of pheromone bombykol and its three geometrical isomers

Norio Miyaura, Hiroshi Suginome, Akira Suzuki

Journal:

Year:

1983

Language:

english

File:

PDF, 490 KB

english, 1983

34

Dimerization of anilines and benzylamines with mercury(II) oxide-iodine reagent

Kazuhiko Orito, Takahiro Hatakeyama, Mitsuhiro Takeo, Shiho Uchiito, Masao Tokuda, Hiroshi Suginome

Journal:

Year:

1998

Language:

english

File:

PDF, 417 KB

english, 1998

35

Tandem cyclization of N-allylaminyl radicals: Stereoselective synthesis of 1,2,5-trisubstituted pyrrolizidines

Hisanori Senboku, Yoshinori Kajizuka, Hikaru Hasegawa, Hirotake Fujita, Hiroshi Suginome, Kazuhiko Orito, Masao Tokuda

Journal:

Year:

1999

Language:

english

File:

PDF, 518 KB

english, 1999

36

Regio- and stereoselective synthesis of (Z)-β-silylalkenylboranes by silaboration of alkynes catalyzed by palladium and platinum complexes

Michinori Suginome, Takanori Matsuda, Hiroshi Nakamura, Yoshihiko Ito

Journal:

Year:

1999

Language:

english

File:

PDF, 806 KB

english, 1999

37

New preparation of reactive zinc metal by electrolysis and its use for a facile isoprenylation of aldehydes and ketones

Masao Tokuda, Nobuo Mimura, Tamae Karasawa, Hirotake Fujita, Hiroshi Suginome

Journal:

Tetrahedron Letters

Year:

1993

Language:

english

File:

PDF, 239 KB

english, 1993

38

Stereoselective cyclization of δ-alkenylamines catalyzed with butyllithium. Synthesis of cis-N-methyl-2,5-disubstituted pyrrolidines

Hirotake Fujita, Masao Tokuda, Makoto Nitta, Hiroshi Suginome

Journal:

Tetrahedron Letters

Year:

1992

Language:

english

File:

PDF, 202 KB

english, 1992

39

Photoinduced oxygenation of dehydrorotenones

Hiroshi Suginome, Tomonori Yonezawa, Tadashi Masamune

Journal:

Tetrahedron Letters

Year:

1968

Language:

english

File:

PDF, 165 KB

english, 1968

40

Structures of two major products in hypoiodite reaction of 3α- and 3β-hydroxy-Δ5-steroids. A correction.

Hiroshi Suginome, Akio Furusaki, Kimitoshi Kato, Takeshi Matsumoto

Journal:

Tetrahedron Letters

Year:

1975

Language:

english

File:

PDF, 207 KB

english, 1975

41

A new stereo- and regioselective synthesis of (±)-sesamin involving a β-scission of alkoxyl radicals as the key step1

Kazuhiko Orito, Kaoru Yorita, Hiroshi Suginome

Journal:

Tetrahedron Letters

Year:

1991

Language:

english

File:

PDF, 254 KB

english, 1991

42

New stereospecific syntheses of pheromone bombykol and its three geometrical isomers

Norio Miyaura, Hiroshi Suginome, Akira Suzuki

Journal:

Tetrahedron Letters

Year:

1983

Language:

english

File:

PDF, 231 KB

english, 1983

43

Cyclization of 1,4-dines in an rf plasma, an apparent di-π-methane rearrangement

Masao Tokuda, Hiroshi Suginome, L.L. Miller

Journal:

Tetrahedron Letters

Year:

1982

Language:

english

File:

PDF, 223 KB

english, 1982

44

New general synthesis of medium-sized lactones: A new entry tothe synthesis of (+−)-phoracantholide I [(+−)-decan-9-olide]

Hiroshi Suginome, Shinji Yamada

Journal:

Tetrahedron Letters

Year:

1985

Language:

english

File:

PDF, 279 KB

english, 1985

45

Fragmentation in hypoiodite and the related alkoxyl radical-involving reactions of alcohols with nitrogen attached to the β-carbon.

Hiroshi Suginome, Hiroaki Umeda, Tadashi Masamune

Journal:

Tetrahedron Letters

Year:

1970

Language:

english

File:

PDF, 189 KB

english, 1970

46

Photolysis of 11-nitrite esters of veratrobasine

Hiroshi Suginome, Iwao Yamazaki, Hitoshi Ono, Tadashi Masamune

Journal:

Tetrahedron Letters

Year:

1968

Language:

english

File:

PDF, 177 KB

english, 1968

47

Photolysis of nitrites of 30,N-diacetyl-22,27-imino-17, 23-oxidojervan-5-ene-3β, 11α-and -3β,11β-diols

Hiroshi Suginome, Norio Sato, Tadashi Musamune

Journal:

Tetrahedron Letters

Year:

1967

Language:

english

File:

PDF, 249 KB

english, 1967

48

One-step formation of furo[3,2-c]quinolin-4(5H)-ones by a new regioselective [2+3] photoaddition of methoxy-substituted 4-hydroxyquinolin-2-one with alkenes1

Hiroshi Suginome, Shinzo Seko, Atsushi Konishi, Kazuhiro Kobayashi

Journal:

Tetrahedron Letters

Year:

1991

Language:

english

File:

PDF, 179 KB

english, 1991

49

Aminyl radical cyclization by means of anodic oxidation. Stereoselective synthesis of cis-1-methyl-2,5-disubstituted pyrrolidines

Masao Tokuda, Yasufumi Yamada, Toshiya Takagi, Hiroshi Suginome, Akio Furusaki

Journal:

Tetrahedron Letters

Year:

1985

Language:

english

File:

PDF, 233 KB

english, 1985

50

A simple new general synthesis of macrocyclic ketones: A new entry to the synthesis of exaltone and (±)-muscone

Hiroshi Suginome, Shinji Yamada

Journal:

Tetrahedron Letters

Year:

1987

Language:

english

File:

PDF, 245 KB

english, 1987

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